Journal of Polymer Science Part A Polymer Chemistry · 2001 · 31 citations · 7 references
Natural SciencesChemical EngineeringChemistryOrganic ChemistryPolymer ChemistryPolymer EngineeringOrganic AcidsPolymer StabilityPolymer StabilizationPolymerization ChemistryAnhydride ReactivityMixed AnhydridesPolyanhydride DegradationPolyanhydridesPolymerization ReactionsRoom Temperature StabilityRoom-temperature StorageStabilizer Effects
Abstract Disproportionation of the liquid mixed anhydride dimethacrylic sebacic anhydride (m‐SA) to methacrylic anhydride and polyanhydride oligomers, as well as vinylic polymerization, can occur on workup and storage at room temperature. Dimethacrylic 1,3‐bis( p ‐carboxyphenoxy) propane, being a solid, can also disproportionate, but the propensity to do so is lower than for m‐SA. These events can be suppressed with free‐radical inhibitors, and the inhibitor 2+3‐ t ‐butyl‐4‐methoxyphenol is a more effective stabilizer than 4‐methoxyphenol at 20 °C. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 4189–4195, 2001
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Organic chemistry of synthetic high polymers
M. J. Perkins · Journal of the Franklin Institute · 1968 · 355 citations