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A novel method for stereospecific generation of natural C-17 stereochemistry and either C-20 epimer in steroid side chains by palladium-catalyzed hydrogenolysis of C-17 and C-20 allylic carbonates.

EngineeringNatural C-17 StereochemistryC-20 Allylic CarbonatesOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisChemistryAsymmetric CatalysisC-20 EpimerEnantioselective SynthesisBiomolecular Engineering