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Studies on the biosynthesis of bialaphos (SF-1293). 9. Biochemical mechanism of C-P bond formation in bialaphos: Discovery of phosphoenolpyruvate phosphomutase which catalyzes the formation of phosphonopyruvate from phosphoenolpyruvete.

C-p Bond FormationBiosynthesisBiochemistryPhosphoenolpyruvate PhosphomutaseBioenergeticsBiocatalysisNatural SciencesEnzyme CatalysisMolecular BiologyNatural Product BiosynthesisChemical BiologyBiochemical MechanismProtein Phosphorylation