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Aminolysis of sulfinamoyl-esters, -sulfonamides and -sulfones. Thiooxamate and thiourea formation via a sulfine intermediate. Thiophilic or carbophilic reaction?

EngineeringBiochemistryNatural SciencesEnzyme CatalysisCarbophilic ReactionOrganic ChemistryThiourea FormationSulfine IntermediateChemistrySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering