Concepedia

A Ga4N8 cage structure formed by reaction of trimethylgallium with phenylhydrazine

David W. Peters, Maurice P. Power, David W. Peters, Edith Bourret, John Arnold

Chemical Communications · 1998 · 39 citations · 7 references

DOI

Concepts

Abstract

Methane elimination during thermolysis of GaMe3 with PhHNNH2 yields sequentially dimeric [Me2Ga{µ-N(H)N(H)Ph}]2, tetrameric [MeGa{µ-N(H)NPh}]4 and, ultimately, GaN; the X-ray structure of the tetramer shows a novel Ga4N8 cage.

References

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Deborah A. Neumayer, Alan H. Cowley, A. Decken et al. · Inorganic Chemistry · 1995 · 51 citations

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Synthesis and Structure of a Novel Lewis Acid−Base Adduct, (H<sub>3</sub>C)<sub>3</sub>SiN<sub>3</sub>·GaCl<sub>3</sub>, en Route to Cl<sub>2</sub>GaN<sub>3</sub> and Its Derivatives:  Inorganic Precursors to Heteroepitaxial GaN

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Lewis Base Adduct Stabilized Organogallium Azides:  Synthesis and Dynamic NMR Spectroscopic Studies of Novel Precursors to Gallium Nitride and Role of Ammonia as Reactive Carrier Gas

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Synthesis and Characterization of (Pentafluorophenyl)amino-Based Amino- and Iminometallanes. Crystal Structures of (MeAlNC6F5)4 and NHC6F5Ga(MesGa)3(.mu.3-NC6F5)4 (Mes = 2,4,6-Me3C6H2)

Thomas Belgardt, Said D. Waezsada, Herbert W. Roesky et al. · Inorganic Chemistry · 1994 · 42 citations · Full text

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