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A spectral study of bis-2,2′-bipyridyl complexes of iron, ruthenium, and osmium
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1966
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Materials ScienceInorganic ChemistryChemical EngineeringElectronic SpectraEngineeringMetal-reduction SpectraNatural SciencesCoordination ComplexSpectral StudyBis-2,2′-bipyridyl ComplexesSpectra-structure CorrelationPhysical ChemistryMolecular ComplexChemistryQuantum ChemistryElectronic Spectral BandsInorganic Compound
Electronic spectra have been recorded for a series of octahedral compounds [M(bipy)2X2] and [M(bipy)2X2]X′, where M = Fe, Ru, and Os, X,X′= Cl, Br, and I, and X2= 2,2′-bipyridyl. Certain of the electronic spectral bands have been assigned to metal-oxidation and metal-reduction spectra. Shifts in these bands have, in some cases, been correlated with the bonding between metal and ligand.