Nontypical Brønsted Acids and Bases

Abstract

The article refers to redox systems exhibiting some uncommon properties as non-monotonic or segmented pH changes affected by addition of some reagents. All the data were obtained on the basis of simulated titrations made according to the iterative computer program MINUIT. The calculation procedure, when made according to the generalized approach suggested by the author, enables one to reconstruct any analytical prescription and apply all attainable physicochemical data involved.