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Electrochemical Synthesis of N-Oxopyridine-2-thionate Complexes of Cd(II): The Crystal Structure of Bis(2,2′-bipyridine)(N-oxopyridine-2-thionate) Cadmium(II) Perchlorate 1/4 (Bipyridine)

M.R. Bermejo, J. Romero, J. A. García-Váquez, A. Sousa, A. Brodbeck, A. Castiñeiras, Wolfgang Hiller, Joachim Strähle

Zeitschrift für Naturforschung B · 1993 · 12 citations · 0 references

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Concepts

Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistryOrganometallic ChemistryCoordination ChemistryCrystal ChemistryElectrochemical SynthesisMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesBioinorganic Coordination ChemistryCadmium ChemistryElectrochemical OxidationElectronic Structure Of Metal ComplexesLanthanide Coordination ChemistryPerchlorate Salts

Abstract

The electrochemical oxidation of Cd in acetonitrile solution of 1-hydroxy-2-pyridinethione (HPT) and 2,2′-bipyridine (bipy) affords [Cd(PT) 2 (bipy)] · H 2 O and [Cd(PT)(bipy) 2 ]ClO 4 · 1/4(bipy). The crystal structure of the perchlorate salt shows the molecule to have a distorted octahedral CdN 4 OS skeleton.