Modeling phase equilibria and speciation in mixed-solvent electrolyte systems

Statistical thermodynamics of liquid mixtures: A new expression for the excess Gibbs energy of partly or completely miscible systems

D. S. Abrams, John M. Prausnitz · AIChE Journal · 1975 · 4.6K citations

Natural Sciences, Chemical Engineering, Chemistry +17

Thermodynamics of electrolytes. I. Theoretical basis and general equations

Kenneth S. Pitzer · The Journal of Physical Chemistry · 1973 · 3.4K citations · Full text

Natural Sciences, Chemistry, Chemical Kinetics +14

Theoretical prediction of the thermodynamic behavior of aqueous electrolytes by high pressures and temperatures; IV, Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600 degrees C and 5kb

H. C. Helgeson, D. H. Kirkham, G Flowers · American Journal of Science · 1981 · 1.8K citations

Natural Sciences, Chemistry, Earth Sciences +17

Inorganic species in geologic fluids: Correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes

Everett L. Shock, David Sassani, Marc Willis et al. · Geochimica et Cosmochimica Acta · 1997 · 1K citations · Full text

Natural Sciences, Earth Sciences, Geology +17

Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Correlation algorithms for ionic species and equation of state predictions to 5 kb and 1000°C

Everett L. Shock, Harold C. Helgeson · Geochimica et Cosmochimica Acta · 1988 · 1K citations

Natural Sciences, Chemistry, Physics +17