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An efficient enantioselective method for asymmetric Michael addition of nitroalkanes to α,β-unsaturated aldehydes
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Citations
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References
2008
Year
Lithium AcetateEfficient Enantioselective MethodEngineeringBiochemistryNatural SciencesCatalytic Synthesisβ-Unsaturated AldehydesOrganic ChemistryCatalysisBeta-unsaturated AldehydesChemistryAsymmetric Michael AdditionAsymmetric CatalysisGood YieldSynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
The addition of nitroalkanes to alpha,beta-unsaturated aldehydes under the catalysis of (S)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine and lithium acetate as additive afforded gamma-nitroaldehydes in good yield and up to 97% ee.
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