Amorphous and crystalline phase interaction during the Brill transition in nylon 66

Abstract

A prominent process in specifically treated nylon 66 and microcomposite samples is identified by dynamic mechanical analysis and proposed to be an amorphous phase counterpart of the Brill transition identified by synchrotron wide-angle X-ray diffraction (WAXD). It is suggested that this process, which marks a critical free volume change and an onset of segmental chain movement in the amorphous phase, precedes and prompts the Brill transition in the crystalline phase.