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Stereoselective Rh<sup>I</sup>-Catalyzed Tandem Conjugate Addition of Boronic Acids−Michael Cyclization
39
Citations
10
References
2007
Year
Enantioselective SynthesisEnones-michael CyclizationEngineeringHeterocyclicNatural SciencesDiversity-oriented SynthesisBoronic AcidsStereoselective FashionOrganic ChemistryStereoselective SynthesisChemistryAsymmetric CatalysisBoronic Acids−michael CyclizationBiomolecular Engineering
The first examples of the stereoselective sequence RhI-catalyzed tandem conjugate addition of boronic acids to enones-Michael cyclization, is reported. The reaction is carried out in dioxane-H2O at rt, and 1,2,3-trisubstituted indans are obtained in a highly regio- and stereoselective fashion.
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