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Tl<sup>I</sup>[C(SiMe<sub>3</sub>)<sub>3</sub>]—An Alkylthallium(<scp>I</scp>) Compound with a Distorted Tetrahedron of Tl Atoms in the Solid State
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Citations
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References
1997
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Thallium TetrahedronInorganic ChemistryWeak Thallium–thallium InteractionsCrystal StructureEngineeringPhysicsCrystalline AlkylthalliumNatural SciencesStructure ElucidationPhysical ChemistryDistorted TetrahedronTl AtomsChemistryQuantum ChemistryMain Group ChemistryCrystallographySolid StateInorganic Compound
Weak thallium–thallium interactions are present in the thallium tetrahedron of the crystalline alkylthallium( I ) compound Tl[C(SiMe 3 ) 3 ], which is easily accessible from cyclopentadienylthallium( I ) and tris(trimethylsilyl)methyllithium. In solution, however, only the monomer of the extremely thermally sensitive compound can be detected.
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