Alkali Metal Fluorides in Organic Synthesis

Abstract

Some applications of alkali metal fluorides in organic synthesis are reviewed. The use of alkali metal fluorides as catalysts in the reactions of fluorine-containing compounds is also discussed. 1. Introduction 2. Elimination of Hydrogen Halides 3. Michael and Knoevenagel Reactions 4. Decarboxylation 5. Reactions of Fluorine-Containing Compounds 5.1. Reactions of Polyfluoroolefins 5.2. Polymerisation 5.3. Reactions of Carbonyl-Containing Compounds 5.4. Reactions with Halogens