Angewandte Chemie International Edition · 1999 · 40 citations · 0 references
Natural SciencesChemistryInorganic ChemistryOrganic ChemistryPolymer ChemistryCoordination ChemistryCoordination PolymersLigand BindingMain-group ChemistryStructural ElucidationCoordination Polymer SynthesisMain-group PhosphidesMetal-ligand Coordination PolymersX-ray Diffraction AnalysisX-ray Structure Determination
Monomeric polyhapto-bound phospholyl compounds were hitherto unknown for the main group elements. Use of a solution of metastable GaBr has allowed the synthesis of monomeric η5-phospholylgallium, which has been characterized by X-ray structure analysis as the Cr(CO)5 complex 1.