Proceedings of the Physical Society · 1960 · 75 citations · 17 references
Natural SciencesElectrical EngineeringPhysicsAtmospheric ElectricityElectrochemistryInorganic ChemistryAtmospheric IonizationElectric PotentialCarbon DioxideCarbon Dioxide EffectsElectric Field Thresholds For BreakdownGas Pressure Effects
The growth of pre-breakdown currents in uniform field conditions has been studied in carbon dioxide at different pressures in the E/p range of 1200 to 26 v cm-1 (mm Hg)-1. Experimental measurements of the Townsend ionization coefficient α show good agreement with the earlier measurements in the E/p range of 1200 to 100 v cm-1 (mm Hg)-1 and with the recent measurements in the E/p range of 70 to 50 v cm-1 (mm Hg)-1. The results show that earlier measurements neglecting attachment may be in error below E/p = 50 v cm-1(mm Hg)-1. It is suggested that the mechanism of negative ion formation is due to dissociative attachment, consequently the growth of current at constant E/p can be represented by the appropriate modification of the Townsend equation. Employing this equation, values of α and the dimensionally equivalent attachment coefficient η have been computed. Further, static breakdown potentials have been measured up to pd (pressure × gap length) similar 1500 mm Hg cm and the values of secondary coefficient γ have been calculated using the modified Townsend breakdown criterion.
17
Ionization and Dissociation of Diatomic Molecules by Electron Impact
H. D. Hagstrum, John T. Tate · Physical Review · 1941 · 206 citations
Natural Sciences, Chemistry, Physics +16
The Heat of Dissociation of CO and the Electron Affinity of O
W. W. Lozier · Physical Review · 1934 · 117 citations
Natural Sciences, Chemistry, Physics +12