Concepedia

Novel Inorganic Ring Systems and Fixation of the S Ion:[(S<sub>6</sub>)Cu(S<sub>8</sub>)Cu(S<sub>6</sub>)]<sup>4⊖</sup> and [Cu<sub>3</sub>(S<sub>4</sub>)<sub>3</sub>]<sup>3⊖</sup>

Achim Müller, Friedrich‐Wilhelm Baumann, Hartmut Bögge, Michael Römer, Erich Krickemeyer, K.R. Schmitz

Angewandte Chemie International Edition in English · 1984 · 35 citations · 7 references

DOI

Concepts

Abstract

Novel CuS Anions with ring structures demonstrate, once again, the unusually versatile coordination behavior of polysulfide ions. [Cu3(S4)3]3⊖ 1, with a central (CuS)3 six-membered ring, and [(S6)Cu(S8Cu(S6)]4⊖ 2, with an S8 chain, were obtained by reaction of Cu(OAc)2 with S8 and H2S, respectively.

References

7

Disulfur complexes

Achim Müller, Wolfram Jaegermann, John H. Enemark · Coordination Chemistry Reviews · 1982 · 225 citations

[Cu<sub>12</sub>S<sub>8</sub>]<sup>4⊖</sup>: A Closed Binary Copper(<scp>I</scp>) Sulfide Cage with Cuboctahedral Metal and Cubic Sulfur Arrangements

P. Betz, Bernt Krebs, Gerald Henkel · Angewandte Chemie International Edition in English · 1984 · 67 citations

, , +16

Novel soluble cyclic and polycyclic polysulfido species: [Au2S8]2-, [Cu4Sx]2- (x = 13−15) and other copper clusters

Achim Müller, Michael Römer, Hartmut Bögge et al. · Inorganica Chimica Acta · 1984 · 56 citations

, , +12

[Cu3S18]3−, a novel sulfur rich complex with different kinds of puckered copper sulfur heterocycles, a central Cu3S3 and three outer CuS6 ones

Achim Müller, Uwe Schimanski · Inorganica Chimica Acta · 1983 · 46 citations

, , +13

Synthesis and Structure of [Ph<sub>4</sub>As][AuS<sub>9</sub>], a Cyclic Nonasulfidoaurate(<scp>I</scp>)

Gerolf Marbach, Joachim Strähle · Angewandte Chemie International Edition in English · 1984 · 30 citations

, , +12