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Reaction of 3,5,7-triphenyl-4H-1,2-diazepine with di-iron nonacarbonyl; the X-ray crystal and molecular structure of a novel iron-containing bicyclo[5,1,1]-system
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1970
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X-ray CrystallographyInorganic ChemistryX-ray CrystalEngineeringHeterocyclicBiochemistryDi-iron Nonacarbonyl3,5,7-Triphenyl-4h-1,2-diazepine LeadsNatural SciencesCoordination ComplexOrganic ChemistryN–n BondOrganometallic CatalysisChemistryHeterocycle ChemistryNovel Iron-containing BicycloInorganic Compound
Reaction of Fe2(CO)9 with 3,5,7-triphenyl-4H-1,2-diazepine leads to cleavage of the N–N bond and formation of a nitrogen bridged complex which has been shown by X-ray crystallography to be a bicyclo[5,1,1]derivative.