Inorganic Chemistry · 2000 · 26 citations · 48 references
Natural SciencesChemistryInorganic ChemistryOrganometallic ChemistrySolid-state ChemistryCoordination ChemistryInorganic SynthesisMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesBonding In Coordination CompoundsComplexation Chemistry
New groups 4 and 5 imido complexes derived from the diamidoamine ligand Me3SiN(CH2CH2NSiMe3)2 (N2N) are described. Reactions of Li2[N2N] with [Ti(NR)Cl2(py)3] gave compound 1 in which the N2N ligand adopts a fac-coordination mode. With [Nb(NtBu)Cl3(py)2], two different Nb(V) products were formed.
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