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Efficient Enantioselective Hydrosilylation of Ketones Catalyzed by Air Stable Copper Fluoride−Phosphine Complexes
129
Citations
9
References
2001
Year
Fluoride-chiral Diphosphine SystemsChemical EngineeringPractical ProtocolEngineeringKetones CatalyzedEfficient Enantioselective HydrosilylationOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisEnantioselective SynthesisOxygen Acceleration Effect
[reaction: see text] Copper(II) fluoride-chiral diphosphine systems catalyze the hydrosilylation of several ketones with moderate to excellent enantioselectivities. An oxygen acceleration effect was observed and led to a practical protocol with low catalyst loading.
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