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Cobalt-Catalyzed Intramolecular Heck-Type Reaction of 6-Halo-1-hexene Derivatives
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Citations
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References
2002
Year
6-Iodo-1-hexene DerivativesHalogenationCross-coupling ReactionDerivativesEngineering6-Halo-1-hexene DerivativesOrganic ChemistryOrganometallic CatalysisCatalysisChemistryTrimethylsilylmethyl Grignard ReagentPharmacologyDerivative (Chemistry)Good Yields
[reaction: see text] Treatment of 6-iodo-1-hexene derivatives with trimethylsilylmethyl Grignard reagent in the presence of CoCl(2)(dppb) in refluxing THF affords Heck-type products, methylenecyclopentanes, in good yields.
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