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A rapid and efficient cycloaddition of simple imines with activated dienes leading to amino sugars; Unusually high “chelation-controlled” diastereoselectivity in the addition to an α,β-dihydroxy imine protected as a ketal.

Activated DienesEngineeringOrganic ChemistrySimple IminesStereoselective SynthesisChelation-controlled ” DiastereoselectivityPharmacologyEnantioselective SynthesisBiomolecular EngineeringNatural Product Synthesis