Asymmetric Michael reaction of α-cyano carboxylates catalyzed by a rhodium complex with trans-chelating chiral diphosphine PhTRAP

Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine

Henri B. Kagan, Tuan-Phat Dang · Journal of the American Chemical Society · 1972 · 1K citations

Natural Sciences, Chemistry, Catalysis +7

Asymmetric synthesis. Production of optically active amino acids by catalytic hydrogenation

Michael D. Fryzuk, B. Bosnich · Journal of the American Chemical Society · 1977 · 545 citations

Natural Sciences, Biochemistry, Chemistry +11

Methodology for the construction of quaternary carbon centers

Stephen F. Martin · Tetrahedron · 1980 · 379 citations

Natural Sciences, Earth Sciences, Geology +5

Practical synthesis of (R)- or (S)-2,2'-bis(diarylphosphino)-1,1'-binaphthyls (BINAPs)

Hidemasa Takaya, Kazushi Mashima, Kinko Koyano et al. · The Journal of Organic Chemistry · 1986 · 368 citations

Natural Sciences, Chemistry, Inorganic Chemistry +5

The asymmetric Michael addition reactions using chiral imines

Jean d’Angelo, Didier Desmaële, Françoise Dumas et al. · Tetrahedron Asymmetry · 1992 · 292 citations

Natural Sciences, Chemistry, Medicinal Chemistry +6