Concepedia

Borane−THF:  New Solutions with Improved Thermal Properties and Stability

Mark Potyen, Kanth V. B. Josyula, Mike Schuck, Sean Lu, Peng Gao, Chris Hewitt

Organic Process Research & Development · 2007 · 18 citations · 11 references

DOI

Concepts

Abstract

A new generation of borane−THF solutions stabilized with 0.005 M of 1,2,2,6,6-pentamethylpiperidine or N-isopropyl-N-methyl-tert-butylamine have been developed. These BTHF solutions show superior stability and reactivity at ambient temperatures when compared to BTHF complex unstabilized or stabilized with 0.005 M NaBH4.

References

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