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An expeditious stereoselective synthesis of functionalized seven-membered carbocycles by reaction of 2-aminobuta-1,3-dienes with vinylchromium fischer type carbenes
31
Citations
9
References
1993
Year
Room TemperatureCross-coupling ReactionSeven-membered CarbocyclesEngineeringHeterocyclicAlkene MetathesisOrganic ChemistryFunctionalized Seven-membered CarbocyclesExpeditious Stereoselective SynthesisChemistryHeterocycle ChemistryStereoselective SynthesisEnantioselective SynthesisBiomolecular EngineeringGood Yields
The reaction between 2-aminobuta-1,3-dienes and pentacarbonyl-[1-methoxy-frans-3-(2-furyl)-prop-2-enylidene]-chromium(0) takes place at room temperature leading with total regio- and stereo-selectivity to functionalized seven-membered carbocycles with good yields.
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