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A homogeneous metallocarborane catalyst: 3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11
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1976
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Inorganic ChemistryHomogeneous Metallocarborane CatalystEngineeringBiochemistryNatural SciencesCoordination ComplexHeterogeneous CatalysisSub 1CatalysisOrganometallic CatalysisChemistryTriphenylphosphine LigandsHomogeneous CatalysisMolecular ComplexTerminal HydrideInorganic SynthesisInorganic Compound
Abstract : C38H42B9P2Rh, monoclinic, P2 (sub 1)/n, a=12.669(6), b=18.587(4), c=16.041(7) A, beta=97.08(4) degrees, Z=4, D sub m=1.29(2)(flotation), D=1.294 g/cc. The Rh(III) ion is complexed by one terminal hydride, one pi-B9C2H11(2-) and two triphenylphosphine ligands. (Author)