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Nickel-Catalyzed Allylation of Allyl Carbonates with Homoallyl Alcohols via Retro-Allylation Providing 1,5-Hexadienes
51
Citations
5
References
2008
Year
Chemical EngineeringCross-coupling ReactionAllyl CarbonatesEngineeringNatural SciencesMild MethodDiversity-oriented SynthesisRetro-allylation Providing 1,5-HexadienesBoc-protected Allyl AlcoholsHomoallyl AlcoholsOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisCatalytic Synthesis
A highly efficient and mild method for the synthesis of 1,5-hexadienes, nickel-catalyzed reactions of Boc-protected allyl alcohols with homoallyl alcohols, has been developed. Nickel-mediated retro-allylation allows for the use of homoallyl alcohols as allylmetal equivalents in the synthesis of 1,5-hexadienes.
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