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Photo-induced water oxidation with tetra-nuclear ruthenium sensitizer and catalyst: A unique 4 × 4 ruthenium interplay triggering high efficiency with low-energy visible light
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Citations
22
References
2010
Year
EngineeringInorganic PhotochemistrySynthetic PhotochemistryChemistryPhotoelectrochemistryChemical EngineeringPhotoredox ProcessLow-energy Visible LightDendrimeric PhotosensitizerPhotocatalysisTetra-nuclear Ruthenium SensitizerTetranuclear RuInorganic ChemistryPhotochemistryMechanistic PhotochemistryRuthenium InterplayPhoto-induced Water OxidationCatalysisPhotoelectrocatalysis
The combined use of a tetranuclear Ru(II) dendrimeric photosensitizer (1) and of a tretraruthenium substituted polyoxotungstate (2) as the catalyst enables photo-induced water oxidation at 550 nm producing O(2) with an outstanding quantum yield of 0.30.
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