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Radical Cation Salts of 1,3,6,8‐Tetrakis(methylthio)‐pyrene—New Easily Accessible Compounds with High Electrical Conductivity and Excellent Stability
37
Citations
11
References
1991
Year
Materials ScienceOrganic Material ChemistryOrganic Charge-transfer CompoundEngineeringElectronic MaterialsOrganic ElectronicsExcellent StabilityApplied PhysicsOrganic SemiconductorMolecule-based MaterialRadical Cation SaltsEasily Accessible CompoundsOrganic ChemistryChemistryInsulator TransitionS Cm−1Perchlorate 1
One of the best one-dimensional small organic conductors is the perchlorate 1 (σ ≤ 677 S cm−1). The corresponding triiodide displays weak metallic conduction; the insulator transition at 45 K is distinctly lower than for TTF-TCNQ. The donor, 1,3,6,8-tetrakis(methylthio)pyrene is easily synthesized in large amounts.
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