Layered Double Hydroxide Surface Modified with (3‐aminopropyl)triethoxysilane by Covalent Bonding

Abstract

Interlayer surfaces of layered double hydroxide (LDH) have been functionalized with amine moieties by condensation between the hydroxyl groups and (3-aminopropyl)triethoxysilane (APS) molecules via the covalent oxane bonds M-O-Si (M=Zn and Cr) (see Figure). Since the galleries of the modified LDHs have a hydrophobic field, various functional molecules such as enzymes, catalysts, and organic molecules can be incorporated between the LDH layers.