Publication | Closed Access
Active site engineering in UiO-66 type metal–organic frameworks by intentional creation of defects: a theoretical rationalization
208
Citations
54
References
2014
Year
EngineeringOrganic ChemistryChemistryChemical EngineeringActive Site EngineeringSynthesis ModulatorsCatalytic ActivityMetal-organic PolyhedronMaterials ScienceInorganic ChemistryIndustrial CatalysisCovalent Bonded FrameworkCatalysisMetal-organic FrameworksCatalytic SynthesisIntentional CreationTheoretical RationalizationUio-66 IncreasesFunctional Materials
The catalytic activity of the Zr-benzenedicarboxylate (Zr-BDC) UiO-66 increases by using synthesis modulators as trifluoroacetate (TFA) or hydrochloric acid (HCl), which can be removed post-synthetically.
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