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Heterolytic C–O cleavage in arylethers activated by [Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)]<sup>+</sup>
26
Citations
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References
1995
Year
Inorganic ChemistryChemical EngineeringAryl EthersEngineeringCoordination ComplexMolecular ComplexCatalysisHeterolytic C–o CleavageChemistryOrganometallic CatalysisC–o BondInorganic Synthesisπ-Phenate Complexes
The C–O bond of Fe(η5-C5H5)+ complexes of aryl ethers is cleaved smoothly by reaction of ButOK in THF or KOH in DME, yielding π-phenate complexes; transetherification can also be achieved in situ at room temperature.
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