Chemical Communications · 2011 · 270 citations · 24 references
Natural SciencesChemistryMaterials ScienceMagnetic MaterialsMaterials ChemistrySolid-state ChemistryLanthanide ChemistryMagnetic Properties Of SolidsMagnetic SusceptibilityMagnetism In SolidsMagnetism Of Inorganic CompoundsMagnetocaloric MaterialsLanthanide ComplexesLanthanide HalidesLanthanide Magnetic PropertiesLanthanide MagnetismLanthanide Single-molecule MagnetsMagnetic PropertiesMagnetocaloric EffectSingle-molecule Magnetism
The synthesis, structure and magnetic properties of two isostructural heptametallic lanthanide discs are reported, showing single molecule magnet (SMM) behaviour with a large energy barrier for the dysprosium analogue and a large magnetocaloric effect (MCE) for the gadolinium analogue.
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Strong exchange and magnetic blocking in N23−-radical-bridged lanthanide complexes
Jeffrey D. Rinehart, Ming Fang, William J. Evans et al. · Nature Chemistry · 2011 · 1.1K citations