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Substituent-induced asymmetry of the cyclopropane ring
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1972
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Microwave SpectroscopyEngineeringConsistent ShorteningHeterocyclicRing TheorySpectra-structure CorrelationPlanar MomentsOrganic ChemistryPhysical ChemistrySubstituent-induced AsymmetryChemistryBiophysics
Analysis of the planar moments of cyclopropyl derivatives studied by microwave spectroscopy indicates a consistent shortening of the C–C bond opposite an unsaturated substituent compared with the corresponding length opposite saturated substituents.