Zeitschrift für Naturforschung B · 1971 · 45 citations · 0 references
Natural SciencesChemistryEnvironmental ChemistryInorganic ChemistryReaction EngineeringChemical ReactionsChemical ReductionOxidation-reduction ReactionsRadical ReactionsRedox ChemistryRedox ProcessesChain Reaction KineticsChain Reaction MechanismsKinetic Data AnalysisOrganic RadiolysisPulse RadiolysisRadiation Chemistry Of Aqueous SolutionsRadiation ReductionRadiation-induced Reaction Mechanisms
The reduction of carbon tetrachloride by hydrated electrons, H atoms and reducing radicals has been investigated by pulse radiolysis conductivity methods. It has been found that one Cl® ion is formed per reducing species. A chain reaction is observed in the γ-radiolysis of solutions of CCl 4 and iso-propanol, diethylether, and tetrahydrofurane. Mechanisms and kinetic data are discussed.