Concepedia

Cyclopentadienyl molybdenum alkyl ester complexes as catalyst precursors for olefin epoxidation

Nidhi Grover, Alexander Pöthig, Fritz E. Kühn

Catalysis Science & Technology · 2014 · 16 citations · 49 references

DOIFull text

Open access

Concepts

Abstract

Piano-stool organomolybdenum complexes of formula [CpMo(CO)<sub>3</sub>(CHR<sup>2</sup>COOR<sup>1</sup>)] are described and applied for olefin epoxidation with <italic>tert</italic>-butyl hydroperoxide as an oxidant.

References

49

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden et al. · Organometallics · 2010 · 3.9K citations

, , +9

<i>ShelXle</i>: a Qt graphical user interface for<i>SHELXL</i>

Christian B. Hübschle, George M. Sheldrick, Birger Dittrich · Journal of Applied Crystallography · 2011 · 3.7K citations · Full text

, , +15

Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron

T. S. Piper, G. Wilkinson · Journal of Inorganic and Nuclear Chemistry · 1956 · 744 citations

, , +8

Methyltrioxorhenium and its applications in olefin oxidation, metathesis and aldehyde olefination

Fritz E. Kühn, Andrea Scherbaum, Wolfgang A. Herrmann · Journal of Organometallic Chemistry · 2004 · 208 citations

, , +10

A Simple Entry to (η<sup>5</sup>-C<sub>5</sub>R<sub>5</sub>)chlorodioxomolybdenum(VI) Complexes (R = H, CH<sub>3</sub>, CH<sub>2</sub>Ph) and Their Use as Olefin Epoxidation Catalysts

Marta Abrantes, Ana M. Santos, J. Mink et al. · Organometallics · 2003 · 145 citations

, , +16