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Complex Interwoven Polymeric Frames from the Self-Assembly of Silver(I) Cations and Sebaconitrile
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1999
Year
Supramolecular AssemblyEngineeringPrototypical Sral2Molecular Self-assemblyMolecular BiologyChemistryDifferent SilverLinear Chain CompoundPolymer ChemistryMaterials ScienceFourfold Interwoven 3DOrganometallic PolymerCrystallographyTransition Metal ChalcogenidesNatural SciencesSelf-assemblyPolymer ScienceApplied PhysicsCoordination PolymerPolymer Self-assembly
Interwoven networks have been isolated from the self-assembly of the flexible long-chain sebaconitrile (1,10-decanedinitrile) and different silver(I) salts. These networks include an eightfold interpenetrated diamondoid frame (I), a fourfold interwoven 3D four-connected frame topologically related to the prototypical SrAl2 (II), an infinitely catenated 2D multilayer (III), and a 3D entangled array (IV).