Optical constants of electrochemically synthesized polyindole and poly(5-carboxilic acid indole)

Abstract

The optical properties and optical constants of the polyindole and poly(5-carboxilic acid indole) conductive polymers synthesized and doped electrochemically with ClO 4 − in acetonitrile solution were investigated by means of transmittance and reflectance spectra, in the wavelength range of 300–800 nm. Absorption band centered at 425 nm assigned to the direct allowed electron transition (π → π*) from valence band to the conduction band. The optical band gap, E g , was determined out of the optical absorption spectra. The E g increases from 2.17 eV for polyindole film to 2.40 eV for poly(5-carboxilic acid indole) polymer thin film, which is attributed to the effect of electron withdrawing carboxylic acid functional group on the growth of chain length of the polymer during the electropolymerization. The oscillator energy E 0, dispersion energy E d and other parameters were determined by the Wemple-DiDomenico method.