Concepedia

A new manifold for the Morita reaction: diene synthesis from simple aldehydes and acrylates/acrylonitrile mediated by phosphines

Anders Palmelund, Eddie L. Myers, Lik Ren Tai, Steve Tisserand, Craig P. Butts, Varinder K. Aggarwal

Chemical Communications · 2007 · 26 citations · 29 references

DOI

Concepts

Abstract

Dienes have been formed with good stereoselectivity and in good yield from simple aldehydes and acrylates/acrylonitrile in the presence of a phosphine and a Lewis acid through a modification of the Morita reaction.

References

29

The Baylis-Hillman reaction: A novel carbon-carbon bond forming reaction

Deevi Basavaiah, Polisetti Dharma Rao, Rachakonda Suguna Hyma · Tetrahedron · 1996 · 858 citations

, , +2

Synthetic potential of the tertiary-amine-catalysed reaction of activated vinyl carbanions with aldehydes

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, , +3

A Tertiary Phosphine-catalyzed Reaction of Acrylic Compounds with Aldehydes

Kenichi Morita, Zennosuke Suzuki, Hiromitsu Hirose · Bulletin of the Chemical Society of Japan · 1968 · 511 citations · Full text

, , +8

Chiral Amine-Catalyzed Asymmetric Baylis<i>−</i>Hillman Reaction:  A Reliable Route to Highly Enantiomerically Enriched (α-Methylene-β-hydroxy)esters

Yoshiharu Iwabuchi, Mari Nakatani, N. Yokoyama et al. · Journal of the American Chemical Society · 1999 · 408 citations

, , +6

New Strategies for the Development of an Asymmetric Version of the Baylis–Hillman Reaction

Peter Langer · Angewandte Chemie International Edition · 2000 · 401 citations

, , +10