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The first structurally characterized organometallic nitrosyl porphyrin: structure of [Ru(ttp)(NO)(C6H4F-p)](ttp =meso-tetratolylporphyrinato dianion)
28
Citations
16
References
1996
Year
X-ray CrystallographyInorganic ChemistryEngineeringBiochemistryNatural SciencesGrignard ReagentsChemical BondCoordination ComplexMolecular BiologyOrganometallic CatalysisOrganometallic Nitrosyl PorphyrinMolecular ComplexChemistryTtp =Meso-tetratolylporphyrinato DianionCrystallographyBiomolecular EngineeringRu–c BondInorganic Compound
Reaction of [Ru(ttp)(NO)Cl] with aryl or alkyl Grignard reagents gives [Ru(ttp)(NO)R](R = C6H4F-p, Me); the Ru–C bond in [Ru(ttp)(NO)Me] undergoes insertion by SO2, and the structure of [Ru(ttp)(NO)(C6H4F-p)] is determined by X-ray crystallography.
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