Concepedia

Bidentate cycloimidate palladium complexes with aliphatic and aromatic anagostic bonds

Stephan Schöler, Maike H. Wahl, Nicole I. C. Wurster, Arik Puls, Christof Hättig, Gerald Dyker

Chemical Communications · 2014 · 31 citations · 28 references

DOI

Concepts

Abstract

Palladium(II) complexes of bidentate cycloimidate ligand systems with a triarylmethyl moiety exhibit exceptional downfield shifts in proton NMR spectra due to rare anagostic interactions.

References

28

Agostic interactions in transition metal compounds

Maurice Brookhart, Malcolm L. H. Green, Gerard Parkin · Proceedings of the National Academy of Sciences · 2007 · 1.1K citations · Full text

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Interactions between CH and NH bonds and d8 square planar metal complexes: hydrogen bonded or agostic?

Wenbin Yao, Odile Eisenstein, Robert H. Crabtree · Inorganica Chimica Acta · 1997 · 257 citations · Full text

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Palladium(II) Complexes of a Sterically Bulky, Benzannulated N-Heterocyclic Carbene with Unusual Intramolecular C−H···Pd and C<sub>c</sub><sub>arbene</sub>···Br Interactions and Their Catalytic Activities

Han Vinh Huynh, Yuan Han, Joanne Hui Hui Ho et al. · Organometallics · 2006 · 239 citations

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NMR Shifts, Orbitals, and M···H−X Bonding in d<sup>8</sup> Square Planar Metal Complexes

Yong Zhang, Jared C. Lewis, Robert G. Bergman et al. · Organometallics · 2006 · 156 citations

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On the Role of Planar Chirality in Asymmetric Catalysis:  A Study toward Appropriate Ferrocene Ligands for Diethylzinc Additions

Carsten Bolm, Kilian Muñiz, Andreas Seger et al. · The Journal of Organic Chemistry · 1998 · 153 citations

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