Acta Crystallographica · 1952 · 20 citations · 0 references
Infinite ChainsEngineeringChemistryTetrahedral BondsInorganic CompoundLinear Chain CompoundStructure ElucidationBiochemistryPhysicsChemical BondUnit CellMercuric AmidobromideQuantum ChemistryHydrogenMolecular ChemistryCrystallographyNatural SciencesHydrogen BondMain Group Chemistry
The structure of HgN-H2Br, similar to that of HgNH~C1, consists of infinite chains of alternating Hg and NH + with linear bonds about Hg and tetrahedral bonds about N. The unit cell is orthorhombic, C~v--P2mm, with a = 5.439, b = 4.487 and c = 6.761 /~.The ttg-l~ bond distance is 2.07 /~.The N-H • • • Br distance is 3.36 /~, based on the assumption that the Br • • • Br distance