Cermets From Thermite Reactions

Abstract

The process whereby the components of a thermite are pressed into a desired shape and ignited to form a cermet is described. In this process, the oxide of the cermet (Al 2 O 3 ) is produced from the oxidation of powdered aluminum and the metallic phase is produced from the resulting reduction of its oxide. A third component (clay, Al 2 O 3 , or MgO) is added to act as a control agent. Methods of compacting and firing are described. A table of oxides reduced by aluminum using this process is presented. The formation of metallic silicides and borides as the metallic phase of a cermet from the appropriate silicates and borates, or metallic oxides with silica or boric acid, is discussed. As an example, ZrSi 2 is produced by the reduction of either ZrSiO 4 or ZrO 2 and SiO 2 , and TiB 2 by the reduction of TiO 2 and B 2 O 3 . The following advantages may be obtained by this method: (1) inexpensive compositions, (2) low ignition temperatures (1800°F.), (3) high reaction temperatures (5000°F.), (4) short firing time (1 hour), and (5) controlled atmosphere unnecessary. A technique was developed whereby cermet test specimens could be prepared from the thermite reaction between aluminum and zirconium silicate. The tensile strength of the finished cermet is given at room temperature and at 2200°F. The apparatus used for determining these tensile strengths is described. Modulus of rupture data also are given. Other oxide thermites were added to the basic zirconium silicate thermite mixture. The effect of these thermite additions on the strength of the basic thermite is described.