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Iron- and manganese-porphyrin catalysed aziridination of alkenes by tosyl- and acyl-iminoiodobenzene
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1984
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Manganese-porphyrin Catalysed AziridinationCross-coupling ReactionEngineeringHeterocyclicBiochemistryAlkene MetathesisNatural SciencesN-substituted AziridinesOrganic ChemistryStereochemical CharacteristicsOrganometallic CatalysisCatalysisAnalogous EpoxidationChemistryHeterocycle ChemistryStereoselective SynthesisAsymmetric Catalysis
N-Substituted aziridines are formed by Fe- or Mn-Porphyrin catalysed reactions of PhlNR compounds (R = tosyl or COCF7) with alkenes; the stereochemical characteristics of these reactions are very different from those of the analogous epoxidation of the alkenes by PhlO.