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Electron diffraction study of gaseous CH(NO2)3 and CCl(NO2)3
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1973
Year
PhysicsElectron SpectroscopyNatural SciencesChemical BondStructure ElucidationElectron Diffraction StudyPhysical ChemistryElectron DiffractionTetrahedral Carbon AtomQuantum ChemistryChemistryC–cl Bond LengthC3 ModelsMolecular Chemistry
The average geometrical structures of CH(NO2)3 and CCl(NO2)3 are consistent with C3 models having similar parameters for C–N, NO, and ONO, and different ones for ∠ NCN; the C–Cl bond length for the tetrahedral carbon atom in CCl(NO2)3(1·712 Å) is the shortest yet found.