Synergistic inhibition effects between leaves and stem extracts of Sida acuta and iodide ion for mild steel corrosion in 1M H2SO4 solutions

Abstract

The synergistic action caused by iodide ions on the corrosion inhibition of mild steel in 1 M H2SO4 by leaves and stem extracts of Sida acuta was studied using weight loss and hydrogen evolution methods at 30–60 °C. It was found that the leaves and stem extracts of S. acuta inhibited the acid induced corrosion of mild steel. Addition of iodide ions enhances the inhibition efficiency to a considerable extent. The inhibition efficiency increases with increase in the iodide ion concentration but decreases with rise in temperature. Adsorption of the extracts alone and in combination of iodide ion was found to obey Freundlich adsorption isotherm at all temperatures studied. Inhibition mechanism is deduced from the temperature dependence of the inhibition efficiency as well as from assessment of kinetic and activation parameters that govern the processes. The synergism parameter (S1) is defined and evaluated from the inhibition efficiency values. This parameter for the different concentrations of iodide ions from the two techniques employed is found to be greater than unity indicating that the enhanced inhibition efficiency of the extracts caused by the addition of iodide ions is due to synergism.