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A Cross-linked Large Channel Organic Coordination Solid
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2001
Year
Materials ScienceOrganic Material ChemistrySupramolecular AssemblyEngineeringSelf-assemblyCovalent Bonded FrameworkTemplate TechniqueMesoscopic Organic MoleculeMolecular MaterialCoordination PolymerChemistryMetal-organic PolyhedronMolecule-based MaterialFunctional MaterialsPolymer ChemistryPhysical Properties
A new approach to fully covalent crystalline networks is revealed. It is a template technique in which a metal salt is co-crystallized with a mesoscopic organic molecule. The Figure shows a phenylacetylenenitrile silver triflate molecule, which is reacted with silyl ditriflates to form high molecular weight polymers. Details of the technique and physical properties are discussed.