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The bovine serum albumin–2-phenylpropane-1,2-diolatodioxo-somium(<scp>VI</scp>) complex as an enantioselective catalyst for cis-hydroxylation of alkenes
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1983
Year
T-butyl HydroperoxideEngineeringAlkene MetathesisBiochemistryNatural SciencesOsmate EsterEnantioselective CatalystOrganic ChemistryOrganometallic CatalysisBovine Serum AlbuminStereoselective SynthesisChemistryBovine Serum Albumin–2-phenylpropane-1,2-diolatodioxo-somiumNatural Product SynthesisAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
The 1:1 complex between an osmate ester and bovine serum albumin was found to be effective as an enantioselective catalyst in the cis-hydroxylation of alkenes, affording diols in up to 68% e.e. and turnover of the catalyst with t-butyl hydroperoxide.