Water Resources Research · 2010 · 54 citations · 57 references
EngineeringEarth SciencesGeologyReservoir EngineeringRock MechanicsSubsurface Fluid FlowClay MineralsPoromechanics Of RocksRock PermeabilityRock PropertiesRock-fluid InteractionsClay Swelling BehaviorDisjoining PressureElectrostatic Disjoining PressurePore PressurePore Pressure DistributionPorosityPressure DifferenceShale Swelling
Electrostatic interactions, associated with negatively charged surfaces of clay minerals, produce a so‐called “disjoining pressure” when diffuse layers overlap, i.e., at low porosity. Disjoining pressure is the pressure difference between the water in the clay pore space and that in a bulk solution at the same depth. Another widely used concept in clay‐rocks is the “swelling pressure.” It corresponds in fact to the macroscopic average of the disjoining pressure. This study proposes to determine the value of the swelling pressure of a natural material by a simple volume‐averaging approach of the disjoining pressure, calculated for each clay mineral present in the material. The swelling pressure, which is dependent on the salinity of the pore fluid, is introduced into a hydrochemomechanical coupling, yielding a more general pressure diffusion equation. The results are compared to swelling pressure measurements for natural shale samples. The implications of this swelling pressure for water pressure measurements in natural formations are also discussed.
57
W. J. Busscher · Soil Science · 1994 · 2.4K citations
How Ions Affect the Structure of Water
B. Hribar, Noel Southall, Vojko Vlachy et al. · Journal of the American Chemical Society · 2002 · 856 citations · Full text