Spontaneous Colorimetric Sensing of the Positional Isomers of Dihydroxynaphthalene in a 1D Organogel Matrix

Pritam Mukhopadhyay, Yuya Iwashita, Michihiro Shirakawa, S. Kawano, Norifumi Fujita, Seiji Shinkai

Angewandte Chemie International Edition · 2006 · 323 citations · 33 references

Concepts

Abstract

Like a color palette: A naphthalenediimide-based organogel colorimetric sensor allows recognition of the positional isomers of dihydroxynaphthalene in the gel phase with the naked eye. Intercalation of the dihydroxynaphthalene into the gel matrix produces a donor–acceptor interaction, which gives the gel a distinct color that depends on the strength of noncovalent (H-bonding, π-stacking, van der Waals) interactions.

References

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